The Transport of Diluted Species Interface

The interface (

), found under the branch (

), is used to calculate the concentration field of a dilute solute in a solvent. Transport and reactions of the species dissolved in a gas, liquid, or solid can be handled with this interface. The driving forces for transport can be diffusion by Fick’s law, convection when coupled to a flow field, and migration, when coupled to an electric field.

The interface supports simulation of transport by convection and diffusion in 1D, 2D, and 3D as well as for axisymmetric components in 1D and 2D. The dependent variable is the molar concentration, c. Modeling multiple species transport is possible, whereby the physics interface solves for the molar concentration, ci, of each species i.

	Some features are only available in a limited set of add-on products. For a detailed overview of which features are available in each product, visit http://www.comsol.com/products/specifications/

The is the default physics interface name.

The is used primarily as a scope prefix for variables defined by the physics interface. Refer to such physics interface variables in expressions using the pattern <name>.<variable_name>. In order to distinguish between variables belonging to different physics interfaces, the name string must be unique. Only letters, numbers, and underscores (_) are permitted in the field. The first character must be a letter.

The default (for the first physics interface in the model) is tds.

If any part of the model geometry should not partake in the mass transfer model, remove that part from the selection list.

Mass transport due to diffusion is always included. Use the check boxes available under to control other transport mechanisms.

Note: Not all additional transport mechanisms listed below are available in all products. For details see http://www.comsol.com/products/specifications/.

•

By default, the check box is selected. Clear the check box to disable convective transport.

•

Select the check box to activate the migration transport of ionic species. See further the theory section Adding Transport Through Migration.

The check box activates functionality specific to species transport in porous media. When selected, the following transport mechanisms are available:

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Select the check box to activate the dispersion mechanism in porous media. See further Dispersion in the theory chapter.

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Select the check box to model volatilization in partially saturated domains. See further Theory for the Transport of Diluted Species Interface.

The following features are also enabled when selecting the check box:

To display this sections, click the button (

) and select .

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When the check box is selected, a weak term that reduces spurious oscillations is added to the transport equation. The resulting equation system is always nonlinear. There are two options for the :

— the default option. This type of crosswind diffusion reduces undershoots and overshoots to a minimum but can in rare cases give equation systems that are difficult to fully converge.

. This option is less diffusive compared to the Do Carmo and Galeão option but can result in more undershoots and overshoots. It is also less effective for anisotropic meshes. The Codina option activates a text field for the glim. It defaults to 0.1[mol/m^3)/tds.helem, where tds.helem is the local element size.

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For both consistent stabilization methods, select an . is the default and means that derivatives of the diffusion tensor components are neglected. This setting is usually accurate enough and is computationally faster. If required, select instead.

To display this section, click the button (

) and select . By default, the check box is not selected, because this type of stabilization adds artificial diffusion and affects the accuracy of the original problem. However, this option can be used to get a good initial guess for under-resolved problems.

To display this section, click the button (

) and select . Normally these settings do not need to be changed. Select a —(the default) or . The conservative formulation should be used for compressible flow. See Convective Term Formulation for more information.

To display this section, click the button (

) and select .

The check box is activated by default so that COMSOL Multiphysics computes predefined accurate boundary flux variables. When this option is checked, the solver computes variables storing accurate boundary fluxes from each boundary into the adjacent domain.

If the check box is cleared, the COMSOL Multiphysics software instead computes the flux variables from the dependent variables using extrapolation, which is less accurate in postprocessing results but does not create extra dependent variables on the boundaries for the fluxes.

The flux variables affected in the interface are:

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ndflux_c (where c is the dependent variable for the concentration). This is the normal diffusive flux and corresponds to the boundary flux when diffusion is the only contribution to the flux term.

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ntflux_c (where c is the dependent variable for the concentration). This is the normal total flux and corresponds to the boundary flux plus additional transport terms, for example, the convective flux when you use the non-conservative form.

Also the check box is available if the previous check box is checked. The smoothing can provide a more well-behaved flux value close to singularities.

For details about the boundary fluxes settings, see Computing Accurate Fluxes in the COMSOL Multiphysics Reference Manual.

The setting should in most pure mass transfer problems be set to , which is the default. It makes sure that the dependent variable does not get affected by small imaginary contributions, which can occur, for example, when combining a Time Dependent or Stationary study with a frequency-domain study. For more information, see Splitting Complex-Valued Variables in the COMSOL Multiphysics Reference Manual.

The dependent variable name is c by default. The names must be unique with respect to all other dependent variables in the component.

Add or remove species variables in the model and also change the names of the dependent variables that represent the species concentrations.

Enter the . Use the (

) and (

) buttons as needed.