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When the Shell type is Layered shell in the Shells Properties section of the parent interface, the same layered material is used in the Lumped System Connector node, but you can limit the contribution to individually selected layers by clearing the Use all layers check box. For a given Layered Material Link or Layered Material Stack, you get access to a list of check boxes for the selection of the individual layers.
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When the Shell type is Nonlayered shell in the Shells Properties section of the parent interface, the Thickness is From physics interface in the Lumped System Connector node. You can change to User defined and override the interface setting with a specific value or expression for Lth.
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See Layered Material, Layered Material Link, Layered Material Stack, Layered Material Link (Subnode), and Single-Layer Materials in the COMSOL Multiphysics Reference Manual.
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