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Zero density gradient as the name suggested.
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Potential barrier adds the quantum confinement effect of an abrupt potential barrier at the boundary. Enter the carrier effective masses (SI unit: kg) the defaults are me_const. Enter the Barrier heights (SI unit: V) the defaults are 0.1[V].
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The functionality of the Surface traps check box in versions prior to 5.4 has been replaced and expanded by the Trap-Assisted Surface Recombination boundary condition.
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