Thermophoresis
The free energy density can have a contribution from the thermal energy. Therefore, the chemical potential in
Equation 3-293
can have the contribution
where
R
is the universal gas constant,
T
is the temperature, and
S
T
is Soret coefficient. The flux from thermophoresis is then defined as a function of the chemical potential,
For linear mobility,
M
is related to the diffusion coefficient
D
as
so the thermophoresis flux reads
It s also possible to define the thermal diffusion coefficient
D
T
=
DS
T
, in which case the thermophoresis flux reads