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1D Lithium-Ion Battery Model Charge Control
Introduction
Charge controllers are useful to improve battery lifetime as they prevent overcharging and possible overvoltage. This model combines the electrochemistry simulation in COMSOL Multiphysics with a control system implemented in Simulink. The control system adjusts the electric current during the charge phase to prevent overvoltage. The electric current is also controlled in the discharge phase to ensure constant power.
Note: This models requires licenses for both the Battery Design Module and LiveLink™ for Simulink®.
Model Definition
The simulation consists of controlling the current in a lithium-ion battery in different cases. In charging mode, the voltage is limited to a maximum value of 4 V. In use, the battery is requested to provide a constant power of 5 W. When the voltage reaches a minimum value of 3.1 V, the current is cut to prevent possible battery damage.
The control system diagram is implemented in Simulink, while the battery’s electrochemical model is computed in COMSOL Multiphysics. Both programs can run together by means of a COMSOL Cosimulation block in the simulation diagram.
The battery cell model is created using the Lithium-Ion Battery interface in COMSOL Multiphysics. A more detailed description on how to set up this type of model can be found in the model example 1D Lithium-Ion Battery Model for the SEI Formation Tutorial in the Battery Design Module Application Library.
The cosimulation with COMSOL Multiphysics and Simulink is set up by exporting a COMSOL Cosimulation file from the COMSOL model, and then adding this to the COMSOL Cosimulation block in the Simulink simulation diagram. The input of the block consists in the applied current, provided by Simulink. The block output is the cell voltage.
Figure 1 below shows the controller diagram implementation in Simulink for both charging and discharging phase.
Figure 1: Charge/discharge control diagram of a battery cosimulation in Simulink.
Results and Discussion
Figure 2 shows the battery voltage variation during the charging and discharging phases.
Figure 2: Battery voltage during charge and discharge.
Figure 3 shows the current in the battery. At the beginning, a constant current of 1.6 A ensures maximal charging. Then, to prevent battery damage, the current is dropped to limit the voltage until full charge. During discharge, the current is adjusted to ensure a utility power of 5 W.
Figure 3: Battery current during charge and discharge.
Figure 4 shows the battery power. You can notice the effect of the PI controller that ensure a constant utility power set to 5W.
Figure 4: Battery power during charge and discharge.
Setting Up the Cosimulation
Follow the workflow below to set up the cosimulation with COMSOL Multiphysics and Simulink:
1
Set up the COMSOL model and make sure that the study runs. Only studies with a single Stationary or Time Dependent study step are supported for cosimulation.
2
Save the COMSOL model. This step is important because the name of the model is needed to load the cosimulation file in Simulink.
3
Add the Cosimulation for Simulink feature node to the COMSOL model. Use this to define the inputs, outputs, and study for the cosimulation.
4
From the Cosimulation for Simulink feature node, export the file for cosimulation. Any location will work, but it is good practice to export this file to the location where the MPH-file has been saved.
5
Create or load the simulation diagram in Simulink, and add the COMSOL Cosimulation block.
6
Double-click the COMSOL Cosimulation block, and enter the name of the cosimulation file exported from COMSOL Multiphysics.
Application Library path: LiveLink_for_Simulink/Tutorials/li_battery_llsimulink
Modeling Instructions — COMSOL Desktop
Start this tutorial by opening a seed file that contains a 1D battery model, without any SEI formation reactions or mechanisms added.
Application Libraries
1
From the File menu, choose Application Libraries.
2
In the Application Libraries window, select Battery Design Module > Lithium-Ion Batteries, Aging and Abuse > sei_formation_seed in the tree.
3
Click  Open.
Parameters 1
1
In the Model Builder window, under Global Definitions click Parameters 1.
2
In the Settings window for Parameters, locate the Parameters section.
3
In the table, append the following settings:
Name
Expression
Value
Description
E_cell_100SOC
4[V]
4 V
Cell voltage at 100% SOC
E_cell_0SOC
3[V]
3 V
Cell voltage at 0% SOC
E_max
4[V]
4 V
Maximum cell voltage in cycling protocol
E_min
3[V]
3 V
Minimum cell voltage in cycling protocol
I
0[A]
0 A
Input current
Ac
0.1[m^2]
0.1 M2
Cross-sectional area
Lithium-Ion Battery (liion)
1
In the Model Builder window, expand the Component 1 (comp1) node, then click Lithium-Ion Battery (liion).
2
In the Settings window for Lithium-Ion Battery, locate the Cross-Sectional Area section.
3
In the Ac text field, type Ac.
Electrode Current 1
1
In the Model Builder window, expand the Lithium-Ion Battery (liion) node.
2
Right-click Lithium-Ion Battery (liion) and choose Electrode Phase > Electrode Current.
3
Select Boundary 4 only.
4
In the Settings window for Electrode Current, locate the Electrode Current section.
5
In the Is,total text field, type I.
6
In the ϕs,bnd,init text field, type E_min.
Definitions
Integration 1 (intop1)
1
In the Definitions toolbar, click  Nonlocal Couplings and choose Integration.
2
In the Settings window for Integration, locate the Source Selection section.
3
From the Geometric entity level list, choose Boundary.
4
Select Boundary 1 only.
Variables 1
1
In the Model Builder window, click Variables 1.
2
In the Settings window for Variables, locate the Variables section.
3
In the table, replace the settings for I_cell and E_cell with the following:
Name
Expression
Unit
Description
I_cell
intop1(reacf(phil))*1[A]
A
Cell current
E_cell
liion.phis0_ec1
V
Cell voltage
To define the cosimulation block output you need to create first a global variable probe.
Global Variable Probe 1 (var1)
1
In the Definitions toolbar, click  Probes and choose Global Variable Probe.
2
In the Settings window for Global Variable Probe, type voltage in the Variable name text field.
3
Locate the Expression section. In the Expression text field, type E_cell.
Study 1
Step 2: Time Dependent
1
In the Model Builder window, under Study 1 right-click Step 2: Time Dependent and choose Delete.
2
In the Study toolbar, click  Compute.
Add Study
1
In the Home toolbar, click  Add Study to open the Add Study window.
2
Go to the Add Study window.
3
Find the Studies subsection. In the Select Study tree, select General Studies > Time Dependent.
4
Right-click and choose Add Study.
5
In the Home toolbar, click  Add Study to close the Add Study window.
Study 2
Step 1: Time Dependent
1
In the Settings window for Time Dependent, locate the Study Settings section.
2
In the Output times text field, type range(0,180,3800).
3
Click to expand the Values of Dependent Variables section. Find the Initial values of variables solved for subsection. From the Settings list, choose User controlled.
4
From the Method list, choose Solution.
5
From the Study list, choose Study 1, Current Distribution Initialization.
6
In the Study toolbar, click  Compute.
Save the COMSOL Model
1
In the Model Builder window, under Results click Probe Plot Group 2.
2
From the File menu, choose Save As.
3
Browse to a suitable folder, enter the filename li_battery_llsimulink.mph, and then click Save.
Exporting the Cosimulation File
In the following configure the cosimulation, and export the file for cosimulation that will be loaded into Simulink.
Global Definitions
Cosimulation for Simulink 1
1
In the Study toolbar, click  Cosimulation for Simulink.
2
In the Settings window for Cosimulation for Simulink, locate the Filename section.
3
In the Filename text field, type li_battery_llsimulink.
4
Locate the Inputs section. Click  Add.
5
In the table, enter the following settings:
Parameter name
Initial value
Unit
I (Input current)
1.621[A]
A
6
Locate the Outputs section. In the table, enter the following settings:
Expression
Unit
Name
comp1.voltage
V
Voltage
7
Click  Export.
Modeling Instructions — Simulink
Once you have created the COMSOL model and saved the cosimulation file you can start Simulink to continue with the setup there.
1
Start COMSOL with Simulink.
2
In MATLAB enter the command mphapplicationlibraries to start the GUI for viewing models from the LiveLink for Simulink application library.
3
Browse to the folder LiveLink_for_Simulink/Tutorials, and select li_battery_llsimulink.slx.
4
Click Open to get the simulation diagram as in Figure 1.
The included COMSOL Cosimulation block is already configured with a cosimulation file based on the model from the COMSOL Application Library and ready to run. If you want to run the simulation directly, go to Step 7 below. Else, if you want to use the model file and cosimulation file you have created by following the steps in the section Modeling Instructions — COMSOL Desktop, you can continue with Step 5 below.
5
Double-click the COMSOL Cosimulation block.
6
In the COMSOL Cosimulation window settings, in the Filename edit field enter the name of the file for cosimulation for Simulink as created in the section Exporting File for Cosimulation for Simulink.
Note: In case the folder path of the file for cosimulation for Simulink is not set in MATLAB enter the full filename.
For this simulation the stop time is set to 8,000 s and the communication step size is set to 50 s.
7
To run the simulation, click Run.