Use the Boundary Pair node to set the periodicity conditions over the boundaries of the
Cell Periodicity domain. This node is only available when the
Boundary condition type in the
Cell Periodicity parent feature is set to
Periodic temperature. In 2D, at least two such pairs are needed, and in 3D at least three pairs. The number of pairs depends on the shape of the unit cell.
Physics tab with Cell Periodicity node selected in the model tree: