Carbon monoxide is part of a reacting mixture. You want to do several things: make use of the predefined expressions of species Cp as an input to the heat capacity of the reacting mixture (
Equation 2-71); use the predefined expression
h for each species to calculate the heat of reaction (
Equation 2-72); and use the predefined expression
s for each species to calculate the entropy of reaction (
Equation 2-73) and subsequently the equilibrium constant of reaction (See
Handling of Equilibrium Reactions).
Polynomials for Cp are available in the literature (
Ref. 2,
Ref. 3, and
Ref. 5) in the frequently used form
You also want to use the predefined expressions h for each species to calculate the heat of reaction (
Equation 2-72). An option is to make use of the heat of formation at standard state (298.15 K) to calculate the coefficient
a6. Identifying the coefficient
a6 of
Equation 2-72 is straightforward. In the NASA polynomial format, the species molar enthalpy is related to its heat capacity according to
Inserting Equation 2-71 into
Equation 2-74, and comparing the result with
Equation 2-72, shows that the term
a6 Rg is identified as the species enthalpy of formation at 0 K, that is,
h(0). Evaluate
h(0) from the species enthalpy of formation at standard state temperature,
Tstd = 298.15 K, which is given by
Carbon monoxide is again part of a reacting mixture. It is satisfactory to approximate Cp as being constant. Specify the species enthalpy by making use of the heat of formation at 298 K,
h(298), according to the well-known expression