The H2 Gas Diffusion Electrode Reaction and
O2 Gas Diffusion Electrode Reaction are available as subnodes to the corresponding
Gas Diffusion Electrode parent nodes.
The Built in option for the
Reference equilibrium potential is based on the reaction stoichiometry and the enthalpies and entropies of the reacting species.
Both the exchange current density and the equilibrium potential of an electrode reaction depend on the partial pressures of the reacting species. By the use of a reference state (a given set of partial pressures) and the Reference equilibrium potential and
Reference exchange current density, analytical expressions such as the
Nernst equation (for the equilibrium potential) and
Mass action law or
Lumped multistep (for the
Butler–Volmer kinetics) may be used to calculate the corresponding partial-pressure dependent values.
Specify the species partial pressures for the reference state used for defining the Reference exchange current density and the
Reference equilibrium potential. The default value (1 atm) refers to standard conditions.
If the Reference equilibrium potential is set to
Built in, the settings of this section only applies to the
Reference exchange current density.
The Built in option for the
Thermoneutral voltage is based on the reaction stoichiometry and the entropies of the reacting species.