To obtain a closed system, the equations include constitutive relations that describe the macroscopic properties of the medium. They are given as
 
    where ε0 and 
μ0 are the permittivity and permeability of vacuum, and 
σ is the electrical conductivity. The constants 
ε0 and 
μ0 are available in COMSOL Multiphysics as predefined physical constants. In the SI units system, 
ε0 has an approximate value of 
1/(36π)·10−9 F/m; 
μ0 has an approximate value of 
4π·10−7 H/m.
 
    The electric polarization vector P describes how the material is polarized when an electric field 
E is present. It can be interpreted as the volume density of 
electric dipole moments. 
P is generally a function of 
E. Some materials can have a nonzero 
P when there is no electric field present.
 
    The magnetization vector M similarly describes how the material is magnetized when a magnetic field 
H is present. It can be interpreted as the volume density of 
magnetic dipole moments. 
M is generally a function of 
H. Permanent magnets, for instance, have a nonzero 
M when there is no magnetic field present.
 
    For linear materials, the polarization is directly proportional to the electric field, P = ε0 χe E , where 
χe is the electric susceptibility. Similarly in linear materials, the magnetization is directly proportional to the magnetic field, 
M = χm H , where 
χm is the magnetic susceptibility. For such materials, the constitutive relations are:
 
    The parameter εr is the relative permittivity and 
μr is the relative permeability of the material. Usually these are scalar properties but can, in the general case, be 3-by-3 tensors when the material is anisotropic. The properties 
ε and 
μ (without subscripts) are the permittivity and permeability of the material, respectively.
 
    
    where Br is the 
remanent magnetic flux density, which is the magnetic flux density when no magnetic field is present.