Using a Fick’s law approximation, the relative mass flux due to molecular diffusion is governed by
In the equations above represents a general diffusion matrix (SI unit: m2/s) describing the diffusion of species
i into the mixture. This form makes it possible to use any diffusion coefficient, matrix, or empirical model based on Fick’s law. For example, in situations when the mass transport is not dominated by diffusion, an alternative is to use the diffusion coefficients at infinite dilution,
When using the Fick’s Law approximation, Additional Transport Mechanisms can be accounted for in the same manner as described above for the mixture-averaged approximation.